In recent years there has been a significant interest in the potential for using seaweed (or macroalgal biomass) for the production of energy, biofuels, and chemicals
through a biorefining approach. This is for a number of reasons.
Firstly, since seaweed is an aquatic biomass, its utilisation does not cause food-vs-fuel
or land-use conflicts,
both of which can occur when land or biomass which could be used for food production is instead used for energy. Also, since seaweed is a fast growing feedstock that does not
an existing resource that can be potentially harvested over several harvest cycles over the year in numerous locations around the world, it is an abundant existing biomass resource
that can make a significant contribution to the bioeconomy and targets regarding bioenergy, biofuels, and bio-products.
Additionally, the chemistry of seaweed constituents offer the
potential to extract numerous high value chemicals many of which could not be sourced from lignocellulosic biomass.
Seaweed Composition
Seaweed composition differs greatly from that of lignocellulosic biomass. For instance, while lignin forms a significant proportion of
lignocellulose, it is absent in seaweed. The other two constituents of lignocellulose are cellulose and hemicellulose, however in seaweed hemicellulose is also absent and, whilst
cellulose can be present in
much smaller amounts, different polysaccharides predominate.
In many of these polysaccharides, sugars that are not present in lignocellulose, or are only present in small amounts,
are present in significant quantities. For example, uronic acids are much more prevalent in seaweed, including
mannuronic acid and guluronic acid which are absent from most lignocellulosic biomasss. The deoxy sugars
fucose and rhamnose are also much more prevalent in seaweed, as is the sugar alcohol
mannitol.
In addition to being significantly different from lignocellulose, the chemistry of seaweeds can also vary greatly between different species. Seaweeds are classed
into three main groups (brown (Phaeophyceae), red (Rhodophyceae), and green (Chlorophyceae)) and there are characteristic differences between each type.
Analysis of Brown Seaweed
Brown seaweeds have been particularly focussed on in recent years as potential biorefinery feedstocks. Laminaria digitata and Saccharina latissima
are examples of brown seaweeds.
Laminarin is one of the polysaccharides found in brown seaweeds. It functions
primarily as a carbohydrate reserve and consists of
a mainchain of glucose with some side chains, also of glucose. The degree of polymerisation of this polysaccharide is around 25, with either mannitol
or glucose as the terminal sugar. Mannitol is also another important cabrohydrate reserve in brown seaweeds.
Fucoidans are another major polysaccharide in brown seaweed. They consist of a backbone of sulphated fucose with additional substitutions
involving galactose and acetate.
Alginic acid is a brown seaweed polysaccharide that contain boths guluronic acid and mannuronic acid
in linear chains with the relative proportions of
mannuronic acid to guluronic acid varying from ratios of 1.2 to 2.1 or greater. Within this linear chain
these hexuronic acids tend to be arranged in C5 epimer blocks of one or the other, although less crystalline blocks involving both sugars can also be present.
Cellulose is only present in minor amounds in brown seaweeds.
Other Constituents and Seasonality in Brown Seaweed
Ash can be a major constituent in brown seaweeds, reaching levels of over 35% in some cases. Protein can also be an important mass component.
It is important to note that the composition of brown seaweed can vary substantially according to species and season. For instance, laminarin can be in concentrations of less than 1%
or over 30%, depending on the season. Similarly, the amount of mannitol can vary by an order of magnitude, whilst alginate can be less than 20% or more than 40%, depending on the
season. Due to this great variation in composition we strongly recommend that samples are analysed directly, for instance with one of our seaweed analysis packages, rather than
using data from the literature.
Analysis of Red Seaweed
Examples of red seaweeds include Kapphaphycus alvarezii, Gracilaria salicornia, and Gelidium amansii.
In red seaweeds the main polysaccharides are agar, carrageenan, cellulose, and mannan. Agar is a mixture of agarose, the major component, and agaropectin. Agarose is a linear
polysaccharide that consists of a backbone of galactose and 3,6-anhydro-galactose, with these two sugars existing as a repeating disaccharide unit. Carrgeenan
also contains these two sugars but they can exist in sulphated and non-sulphated forms. There are different classes of carrageenans and these differ according to the
number and position of the sulphate groups. Mannan is a polysaccharide of mannose and can be sulphated in some cases.
Analysis of Green Seaweed
Examples of green seaweeds include Ulva lactuca and Ulva pertusa.
In green seaweeds the main polysaccharides are cellulose, ulvan, and mannan. The main constituents of ulvan are rhamnose,
xylose, and
glucuronic acid.
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Analysis of Seaweed at Celignis
Our expertise with ion chromatography has allowed us to develop protocols for determining the carbohydrate
and amino acids composition of brown seaweeds.
Analysis package P72 - Seaweed Amino Acids will give the amounts of 12 different amino acids present in seaweed samples.
While these analyses packages are tailored towards the analysis of brown seaweeds we can also analyse red and green seaweeds. Please get in touch if you would like
to find the value of these types of macroalgae.
Celignis is a Partner in 3 Successful Proposals for EU Funding
We are pleased to announce that three of the proposals involving Celignis, submitted to the CBE-JU programme for funding collaborative biomass research in Europe, were successful. These projects will provide an additional funding of €1.5m to Celignis and build on our achievements in other CBE and EU projects. In particular, the projects are all at enhanced TRLs (6/7) and will use our existing Celignis Bioprocess infrastructure and will also fund further development of our bioprocessing capacities and the Bioprocess Development Services we offer our clients.
Details on the funded projects are provided below:
BIONEER - This project was funded under CBE-JU topic IA-06 and focuses on the TRL 6/7 production of biobased platform chemicals. Celignis's activities in the project focus on scaling up the work undertaken in our ongoing
Celignis to Exhibit and Present at Major Biochar Event
The 2024 North American Biochar Conference will take place in Sacramento, California, on Feb 12-15
On Feb 12-15 we'll be exhibiting at the 2024 North American Biochar Conference, taking place at the SAFE Credit Union Convention Centre in Sacramento, California.
We're looking forward to interacting with the 1000+ expected attendees, outlining our extensive range of analytical and application testing services for biochar.
Celignis CIO Lalitha Gottumukkala will also be a member of the expert panel focused on developing improved laboratory methods for biochar characterisation.
This Networking Event Will Involve Discussions on Collaborations for Proposals to the 2024 CBE-JU Topics
The Circular Bioeconomy Europe Joint Undertaking (CBE-JU) is an organisation that funds biomass research in Europe at various Technology Readiness Levels (TRLs). Since 2016 Celignis has been an active participant in a number of projects funded by the CBE-JU.
The Biobased Industries Consortium (BIC) is the steering committee that helps to steer the focus of research for the CBE-JU programme. In 2023 Celignis joined the BIC as a Full Industry Member and participated in several proposals submitted for different research topics in the CBE-JU's 2023 Work Programme.
We're Hiring - Business Administration & Client Relationship Manager
This position will involve working closely with senior management, fostering existing and new client relationships.
Situated in Limerick, Ireland, Celignis currently operates at two centres, Celignis Analytical and Celignis Bioprocess, actively engaging in a variety of private and public bioeconomy projects. As we continue to expand, we're looking to strengthen our team of 14 with a Business Administration and Client Relationship Manager who can bring a blend of enthusiasm and expertise.
This position will involve working closely with senior management, fostering existing and new client relationships, and ensuring successful delivery of our services, playing a key role in our ongoing growth and success.
Celignis to Sponsor and Present at Major Biochar Event
The event takes place on May 3rd at Carrick-on-Shannon
We are pleased to announce that, on May 3rd, Celignis will be presenting and exhibiting at the National Biochar and Carbon Products Conference 2023, which is taking place in Carrick-on-Shannon in County Leitrm, Ireland.
This conference is being organised under the auspices of the Interreg Northwest Europe-funded THREE C Project, entitled 'Creating and sustaining Charcoal value chains to promote a Circular Carbon economy in NWE Europe'.
The conference will highlight both Irish stakeholders who are currently working in the biochar and carbon products sector, but also partners from the THREE C project (covering Netherlands, Luxembourg, Germany, Belgium, France and Wales, as well as Ireland) who have interesting stories and products to share.
Thanks for contacting us. One of our representatives will be in contact with you shortly regarding your inquiry. If you ever have any questions that require immediate assistance, please call us at +353 61 371 725.
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